I looked a little bit at the code and the replaement happens in the Str class of the toolkit: https://github.com/getkirby/toolkit/blob/master/lib/str.php
Through the following array:
static public $ascii = array(
'/Ä/' => 'Ae',
'/æ|ǽ|ä/' => 'ae',
'/œ|ö/' => 'oe',
'/À|Á|Â|Ã|Å|Ǻ|Ā|Ă|Ą|Ǎ|А/' => 'A',
'/à|á|â|ã|å|ǻ|ā|ă|ą|ǎ|ª|а/' => 'a',
'/Б/' => 'B',
'/б/' => 'b',
'/Ç|Ć|Ĉ|Ċ|Č|Ц/' => 'C',
'/ç|ć|ĉ|ċ|č|ц/' => 'c',
'/Ð|Ď|Đ/' => 'Dj',
'/ð|ď|đ/' => 'dj',
'/Д/' => 'D',
'/д/' => 'd',
'/È|É|Ê|Ë|Ē|Ĕ|Ė|Ę|Ě|Е|Ё|Э/' => 'E',
'/è|é|ê|ë|ē|ĕ|ė|ę|ě|е|ё|э/' => 'e',
'/Ф/' => 'F',
'/ƒ|ф/' => 'f',
'/Ĝ|Ğ|Ġ|Ģ|Г/' => 'G',
'/ĝ|ğ|ġ|ģ|г/' => 'g',
'/Ĥ|Ħ|Х/' => 'H',
'/ĥ|ħ|х/' => 'h',
'/Ì|Í|Î|Ï|Ĩ|Ī|Ĭ|Ǐ|Į|İ|И/' => 'I',
'/ì|í|î|ï|ĩ|ī|ĭ|ǐ|į|ı|и/' => 'i',
'/Ĵ|Й/' => 'J',
'/ĵ|й/' => 'j',
'/Ķ|К/' => 'K',
'/ķ|к/' => 'k',
'/Ĺ|Ļ|Ľ|Ŀ|Ł|Л/' => 'L',
'/ĺ|ļ|ľ|ŀ|ł|л/' => 'l',
'/М/' => 'M',
'/м/' => 'm',
'/Ñ|Ń|Ņ|Ň|Н/' => 'N',
'/ñ|ń|ņ|ň|ʼn|н/' => 'n',
'/Ö/' => 'Oe',
'/ö/' => 'oe',
'/Ò|Ó|Ô|Õ|Ō|Ŏ|Ǒ|Ő|Ơ|Ø|Ǿ|О/' => 'O',
'/ò|ó|ô|õ|ō|ŏ|ǒ|ő|ơ|ø|ǿ|º|о/' => 'o',
'/П/' => 'P',
'/п/' => 'p',
'/Ŕ|Ŗ|Ř|Р/' => 'R',
'/ŕ|ŗ|ř|р/' => 'r',
'/Ś|Ŝ|Ş|Ș|Š|С/' => 'S',
'/ś|ŝ|ş|ș|š|ſ|с/' => 's',
'/Ţ|Ț|Ť|Ŧ|Т/' => 'T',
'/ţ|ț|ť|ŧ|т/' => 't',
'/Ü/' => 'Ue',
'/ü/' => 'ue',
'/Ù|Ú|Û|Ũ|Ū|Ŭ|Ů|Ű|Ų|Ư|Ǔ|Ǖ|Ǘ|Ǚ|Ǜ|У/' => 'U',
'/ù|ú|û|ũ|ū|ŭ|ů|ű|ų|ư|ǔ|ǖ|ǘ|ǚ|ǜ|у/' => 'u',
'/В/' => 'V',
'/в/' => 'v',
'/Ý|Ÿ|Ŷ|Ы/' => 'Y',
'/ý|ÿ|ŷ|ы/' => 'y',
'/Ŵ/' => 'W',
'/ŵ/' => 'w',
'/Ź|Ż|Ž|З/' => 'Z',
'/ź|ż|ž|з/' => 'z',
'/Æ|Ǽ/' => 'AE',
'/ß/'=> 'ss',
'/IJ/' => 'IJ',
'/ij/' => 'ij',
'/Œ/' => 'OE',
'/Ч/' => 'Ch',
'/ч/' => 'ch',
'/Ю/' => 'Ju',
'/ю/' => 'ju',
'/Я/' => 'Ja',
'/я/' => 'ja',
'/Ш/' => 'Sh',
'/ш/' => 'sh',
'/Щ/' => 'Shch',
'/щ/' => 'shch',
'/Ж/' => 'Zh',
'/ж/' => 'zh',
);
I haven’t tested anything, but since it is a public static variable maybe you could change it:
str::$ascii = array(); // your array
Not sure if this really works depending on the order and scope of this and when it would get called if you put it e.g. in the config.php.
Edit: okay, I tried it, but it seems not as simple as have it just redefined in the config.php. Maybe someone else has an idea where.
Edit2: no actually it does work, it just treats ‘Ä’ as ‘ä’ when replacing, cause all characters are lowered before replaced anyways.